Numbers 13:22

13:22 When they went up through the Negev, they came to Hebron where Ahiman, Sheshai, and Talmai, descendants of Anak, were living. (Now Hebron had been built seven years before Zoan in Egypt.)

Numbers 13:29

13:29 The Amalekites live in the land of the Negev; the Hittites, Jebusites, and Amorites live in the hill country; and the Canaanites live by the sea and along the banks of the Jordan.”

Numbers 21:1

Victory at Hormah

21:1 When the Canaanite king of Arad who lived in the Negev heard that Israel was approaching along the road to Atharim, he fought against Israel and took some of them prisoner.